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  • 'Frustrated' water molecules drive supramolecular self-assembly – Physics World.

Bert Meijer and postdoc Nathan van Zee. Courtesy: Bart van Overbeeke Although oils only contain trace levels of water molecules, they can direct supramolecular processes by forming new hydrogen bonds. Want to read more?

Supramolecular Assembly Via Hydrogen Bonds I

The sequences of oligomeric molecules equipped with interacting side-chains encode the three-dimensional structure, the supramolecular assembly properties, and ultimately function. In an attempt to replicate the duplex forming properties of nucleic acids, an oligoester containing an alternating sequence of hydrogen bonding donor D and acceptor A residues was synthesised.

hydrogen bonds

Characterisation of assembly properties of the ADAD oligomer revealed a supramolecular architecture that resembles the kissing stem-loops motif found in folded RNA. E-mail: ed. Received Nov Abstract The formation of complex superstructures via hydrogen bonding of two ditopic building blocks, diazadibenzoperylenes 1a,b and isophthalic acid 2, has been investigated.

Open in a separate window. Figure 1. Figure 2. Figure 3. Figure 4.

Figure 5. Figure 6. Supplementary Material Supporting Text: Click here to view. Acknowledgments We thank G. Abbreviation Vis visible. References 1.

Supplementary files

Adv Mater. Angew Chem Int Ed Engl. Adv Funct Mater. J Am Chem Soc. Chem Eur J. J Org Chem. Tetrahedron Lett. Carr, A.

Surface-Based Supramolecular Chemistry Using Hydrogen Bonds | Accounts of Chemical Research

Krishnamohan Sharma, C. Valiyaveettil, S. Pourcain C B. J Mater Chem. Kotera, M. Tschierske C. J Phys Chem. How does Europe PMC derive its citations network?